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Photoelectrochemical solar energy conversion based on blend of poly(3-hexylthiophene) and fullerene

Identifieur interne : 008631 ( Main/Repository ); précédent : 008630; suivant : 008632

Photoelectrochemical solar energy conversion based on blend of poly(3-hexylthiophene) and fullerene

Auteurs : RBID : Pascal:06-0535945

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English descriptors

Abstract

A solid-state photoelectrochemical solar energy conversion device based on blend of poly(3-hexylthiophene) (P3HT) and fullerene (C60) has been constructed and characterized. The photoelectrochemical performance parameters of the device were compared with pure P3HT solid-state photoelectrochemical cell. The current-voltage characteristics in the dark and under white light illumination and photocurrent spectra for front- and backside illuminations have been studied. The following device parameters were obtained: an open-circuit voltage of 97.8mV and a short-circuit current of 7.28 μA/cm2 at light intensity of 100mW/cm2; IPCE% of 0.43% for front side illumination (ITO/PEDOT) and IPCE% of 0.01% for backside illumination (ITO/P3HT:C60). The dependence of the short-circuit current and an open-circuit voltage on the light intensity and time have also been studied.

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Pascal:06-0535945

Le document en format XML

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<title xml:lang="en" level="a">Photoelectrochemical solar energy conversion based on blend of poly(3-hexylthiophene) and fullerene</title>
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<name sortKey="Mengesha, Ushula" uniqKey="Mengesha U">Ushula Mengesha</name>
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<s1>Department of Chemistry, Bahir Dar University, P.O. Box 79</s1>
<s2>Bahir Dar</s2>
<s3>ETH</s3>
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<country>Éthiopie</country>
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<name sortKey="Yohannes, Teketel" uniqKey="Yohannes T">Teketel Yohannes</name>
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<s1>Department of Chemistry, Addis Ababa University, P.O. Box 1176</s1>
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<country>Éthiopie</country>
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<div type="abstract" xml:lang="en">A solid-state photoelectrochemical solar energy conversion device based on blend of poly(3-hexylthiophene) (P3HT) and fullerene (C
<sub>60</sub>
) has been constructed and characterized. The photoelectrochemical performance parameters of the device were compared with pure P3HT solid-state photoelectrochemical cell. The current-voltage characteristics in the dark and under white light illumination and photocurrent spectra for front- and backside illuminations have been studied. The following device parameters were obtained: an open-circuit voltage of 97.8mV and a short-circuit current of 7.28 μA/cm
<sup>2</sup>
at light intensity of 100mW/cm
<sup>2</sup>
; IPCE% of 0.43% for front side illumination (ITO/PEDOT) and IPCE% of 0.01% for backside illumination (ITO/P3HT:C
<sub>60</sub>
). The dependence of the short-circuit current and an open-circuit voltage on the light intensity and time have also been studied.</div>
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<sup>2</sup>
at light intensity of 100mW/cm
<sup>2</sup>
; IPCE% of 0.43% for front side illumination (ITO/PEDOT) and IPCE% of 0.01% for backside illumination (ITO/P3HT:C
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